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邹勃

(教授)
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在职信息:在职
所在单位:物理学院

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个人简介

邹勃,吉林大学超硬材料国家重点实验室教授,博士生导师。

主要从事高压物理和高压化学研究利用自主设计搭建的高压原位吸收、发射、拉曼和红外光谱等多种高压原位光谱实验测量系统和高压原位核磁共振,建立了高压化学实验室。

利用高压这个独特的热力学参量,解决了部分常压下科学中有争议的问题;通过调控化学反应动力学势垒和热力学相变势垒,发现了系列高压相截获的方法,并成功应用在高能密度材料和卤素钙钛矿材料上;成功实现了压致变色材料光学特性的大范围精确调控,提出了压力诱导发光(PIE)的概念发现了新型超大负压缩率材料、提出分子层滑移和酒架状非共价键结构等负压缩新机制为制备具有特定功能的化学材料提供了新思路和新方法。

共发表包括Nature Commun, J Am Chem SocAngew Chem Int Ed等在内的SCI论文300余篇,被SCI论文引用8000余次,H因子为43

 

代表性论文:

 

高压下卤素钙钛矿材料研究

1. Z. Ma, Z. Liu, S. Lu, L. Wang, X. Feng, D. Yang, K. Wang, G. Xiao,* L. Zhang,* S. A. T. Redfern, and B. Zou,* Pressure-Induced Emission of Halide Perovskite Cs4PbBr6 Nanocrystals. Nature Commun. 9 (2018), 4506 (压力诱导发光PIE

2. Y. Shi, Z. Ma, D. Zhao, Y. Chen, Y. Cao, K. Wang, G. Xiao,* and B. Zou,* Pressure-Induced Emission (PIE) of One-Dimensional Organic Tin Bromide Perovskites. J. Am. Chem. Soc. 141 (2019), 6504 (压力诱导发光PIE

3. G. Xiao, Y. Cao, G. Qi, L. Wang, C. Liu, Z. Ma, X. Yang, Y. Sui, W. Zheng, and B. Zou,* Pressure Effects on Structure and Optical Properties in Cesium Lead Bromide Perovskite Nanocrystals. J. Am. Chem. Soc. 139 (2017), 10087

4. Y. Fang, L. Zhang, L. Wu, J. Yan, Y. Lin, K. Wang,* W. L. Mao, and B. Zou, Pressure-Induced Emission (PIE) and Phase Transition of a Two dimensional Halide Double Perovskite (BA)4AgBiBr8 (BA = CH3(CH2)3NH3+). Angew. Chem. Int. Ed. 58 (2019), 15249(压力诱导发光PIE 

5. L. Zhang, C. Liu, L. Wang, C. Liu, K. Wang,* and B. Zou,* Pressure-Induced Emission Enhancement, Band-Gap Narrowing, and Metallization of Halide Perovskite Cs3Bi2I9Angew. Chem. Int. Ed. 57 (2018), 11213 (压力诱导发光PIE

6. Q. Li, Y. Wang, W. Pan, B. Zou,* W. Yang, J. Tang, and Z. Quan,* High Pressure Band Gap Engineering in Lead-Free Cs2AgBiBrDouble Perovskite. Angew. Chem. Int. Ed. 56 (2017), 15969 (高压下带隙截获)

7. Z. Ma, F. Li, D. Zhao, G. Xiao,* and B. Zou,* Whether or not Emission of Cs4PbBr6 Nanocrystals: High-Pressure Experimental Evidence. CCS Chem. 2 (2020), 71(压力解决科学中争议的问题)

8. L. Zhang, Y. Fang, L. Sui, J. Yan, K. Wang,* K. Yuan, W. L. Mao, and B. Zou,* Tuning Emission and Electron-Phonon Coupling in Lead-Free Halide Double Perovskite Cs2AgBiCl6 under Pressure. ACS Energy Lett. 4 (2019), 2975 (压力诱导发光PIE

9. Y. Cao, G. Qi, L. Sui, Y. Shi, T. Geng, D. Zhao, K. Wang, K. Yuan, G. Wu, G. Xiao,* S. Lu,* and B. Zou,* Pressure-Induced Emission Enhancements of Mn2+ Doped Cesium Lead Chloride Perovskite Nanocrystals. ACS Mater. Lett. 2 (2020), 381 (压力诱导发光PIE

10. L. Zhang, L. Wu, K. Wang,* and B. Zou,* Pressure-Induced Broadband Emission of 2D Organic-Inorganic Hybrid Perovskite (C6H5C2H4NH3)2PbBr4Adv. Sci. 6 (2019), 201801628 (压力诱导发光PIE

11. L. Zhang, C. Liu, Y. Lin, K. Wang,* F. Ke, C. Liu,* W. L. Mao,* and B. Zou,* Tuning Optical and Electronic Properties in Low-Toxicity Organic-Inorganic Hybrid (CH3NH3)3Bi2I9 under High Pressure. J. Phys. Chem. Lett. 10 (2019), 1676 (压力诱导发光PIE

12. Q. Li, S. Li, K. Wang, Z. Quan, Y. Meng, and B. Zou,* High Pressure Study of perovskite-like Organometal Halide: Band Gap Narrowing and Structural Evolution of [NH3-(CH2)4-NH3]CuCl4J. Phys. Chem. Lett. 8 (2017), 500

13. L. Wang, K. Wang, and B. Zou,* Pressure-Induced Structural and Optical Properties of Organometal Halide Perovskite Based Formamidinium Lead Bromide. J. Phys. Chem. Lett. 7 (2016), 2556

14. L. Wang, K. Wang, G. Xiao, Q. Zeng, and B. Zou,* Pressure Induced Band Gap Shifts and Structural Evolution of Organometal Halide Perovskite-Based Methylammonium Lead Chloride. J. Phys. Chem. Lett. 7 (2016), 5273

 

高压下负压缩材料研究

1. Q. Zeng, K. Wang,* and B. Zou,* Large Negative Linear Compressibility in InH(BDC)2 from Framework Hinging. J. Am. Chem. Soc. 139 (2017), 15648

2. Q. Zeng, K. Wang,* and B. Zou,* Negative Linear Compressibility, Response to Pressure in Multitype-Wine-Rack Metal-Organic Frameworks. ACS Mater. Lett. 2 (2020), 291

3. Y. Yu, Q. Zeng, Y. Chen, K. Wang,* and B. Zou,* Extraordinarily Persistent Zero Linear Compressibility in Metal-Organic Framework MIL-122(In). ACS Mater. Lett. 2 (2020), 519

4. Q. Zeng, K. Wang, Y. Qiao, X. Li, and B. Zou,* Negative Linear Compressibility due to Layer Sliding in a Layered MOF, J. Phys. Chem. Lett. 8 (2017), 1436

5. Y. Qiao, K. Wang, H. Yuan, K. Yang, and B. Zou,* Negative Linear Compressibility in Organic Mineral Ammonium Oxalate Monohydrate with Hydrogen Bonding Wine-rack Motifs. J. Phys. Chem. Lett. 6 (2015), 2755

 

高压下压致变色材料研究

1. H. Liu, Y. Gu, Y. Dai, K. Wang,* S. Zhang, G. Chen, B. Zou,* and B. Yang,* Pressure-Induced Fluorescence Up-conversion and Enhancement: A Cooperative Effect between Aggregation-Induced Emission and Energy-Transfer Suppression. J. Am. Chem. Soc. 142 (2020), 1153(压力诱导发光PIE

2. J. Wu, Y. Cheng, J. Lan,* D. Wu, S. Qian, L. Yan, Z. He, X. Li, K. Wang, B. Zou,* and J. You,* Molecular Engineering of Mechanochromic Materials by Programmed C–H Arylation: Making a Counterpoint in Chromism Trend. J. Am. Chem. Soc. 138 (2016), 12803

3. Y. Wang, X. Tan, Y. Zhang, S. Zhu, I. Zhang, B. Yu, K. Wang, B. Yang, M. Li,* B. Zou,* and S. X. Zhang,* Dynamic Behavior of Molecular Switches in Crystal under Pressure and Its Reflection on Tactile Sensing. J. Am. Chem. Soc. 137 (2015), 931

4. Y. Liu, Q. Zeng, B. Zou,* Y. Liu, B. Xu*, and W. Tian, Piezochromic Luminescence of Donor—Acceptor Co-crystal: Distinct Responses to Anisotropic Grinding and Isotropic Compression. Angew. Chem. Int. Ed. 57 (2018), 15670

5. Y. Dong, B. Xu, J. Zhang, X. Tan, L. Wang, J. Chen, H. Lv, S. Wen, B. Li, L. Ye, B. Zou,* and W. Tian,* Piezochromic Luminescence Based on the Molecular Aggregation of 9,10-Bis((E)-2-(pyrid-2-yl)vinyl)anthracene. Angew. Chem. Int. Ed. 51 (2012), 10782

6. L. Wang, K. Wang, B. Zou,* K. Ye, H. Zhang,* and Y. Wang, Luminescent Chromism of Boron Diketonate Crystals: Distinct Responses to Different Stresses. Adv. Mater. 27 (2015), 2918

7. S. Zhang, Y. Dai, Y. Gao, S. Luo, K. Wang, B. Zou,* B. Yang,* and Y. Ma, Rehybridization of Nitrogen Atom Induced Photoluminescence Enhancement Under Pressure Stimulation. Adv. Funct. Mater. 27 (2017), 1602276 (压力诱导发光PIE

8. C. Lv, W. Liu, Q. Luo, H. Yi, H. Yu,* Z. Yang, B. Zou,* and Y. Zhang,* Highly Emissive AIE-Active Luminophore Exhibiting Deep-Red to Near-Infrared Piezochromism and High-Quality Lasing. Chem. Sci. 11 (2020), 4007

9. Y. Gu, H. Liu, R. Qiu, Z. Liu, C. Wang, T. Katsura, H. Zhang, M. Wu, M. Yao, H. Zheng, K. Li, Y. Wang, K. Wang,* B. Yang, Y. Ma, and B. Zou,* Pressure-Induced Emission Enhancement and Multi-color for 1, 2, 3, 4-tetraphenyl-1, 3-cyclopentadiene (TPC)Controlled Structure Evolution. J. Phys. Chem. Lett. 10 (2019), 55572 (压力诱导发光PIE

10. Y. Gu, K. Wang,* Y. Dai, G. Xiao, Y. Ma, Y. Qiao, and B. Zou,* Pressure-Induced Emission Enhancement of Carbazole: the Restriction of Intramolecular Vibration. J. Phys. Chem. Lett. 8 (2017), 4191 (压力诱导发光PIE

11. H. Yuan, K. Wang, K. Yang, B. Liu, and B. Zou,* Luminescence properties of compressed tetraphenylethene: the role of intermolecular interactions. J. Phys. Chem. Lett. 5 (2014), 2968 (压力诱导发光PIE

 

纳米材料制备及其在高压下的研究

1. G. Xiao, Y. Wang, D. Han, K. Li, X. Feng, K. Wang, L. Liu, S. A. T. Redfern, and B. Zou,* Pressure-induced Large Emission Enhancements of Cadmium Selenide Nanocrystals. J. Am. Chem. Soc. 140 (2018), 13970 (压力诱导发光PIE

2. G. Xiao, X. Yang, X. Zhang, K. Wang, X. Huang, Z. Ding, Y. Ma, G. Zou, and B. Zou,* A Protocol to Fabricate Nanostructured New Phase: B31-Type MnS Synthesized under High Pressure. J. Am. Chem. Soc. 137 (2015), 10297 (高压相截获)

3. C. Liu, G. Xiao,* M. Yang, B. Zou,* Z. Zhang,* and D. Pang, Mechanofluorochromic Carbon Nanodots: Controllable Pressure-Triggered Blue and Red Shifted Photoluminescence. Angew. Chem. Int. Ed. 57 (2018), 1893

4. S. Lu, G. Xiao, L. Sui, T. Feng, X. Yong, S. Zhu, B. Li, Z. Liu, B. Zou,* M. Jin,* J. S. Tse, H. Yan,* and B. Yang,* Unique Piezochromic Carbon Dots with Two-photon Fluorescence. Angew. Chem. Int. Ed. 56 (2017), 6187 (高压相截获)

5. G. Xiao, C. Zhu, Y. Ma,* B. Liu, G. Zou, and B. Zou,* Unexpected Room-Temperature Ferromagnetism in Nanostructured Bi2Te3Angew. Chem. Int. Ed. 53 (2014), 729

6. B. Zou, B. Ceyhan, U. Simon, and C. M. Niemeyer,* Self-Assembly of Cross-Linked DNA-Gold Nanoparticle Layers Visualized by In Situ Scanning Force Microscopy. Adv. Mater. 17 (2005), 1643

7. Q. Dai, Y. Wang, X. Li, Y. Zhang, D. J. Pellegrino, M. Zhao, B. Zou,* J. Seo, Y. Wang, and W. W. Yu,* Size-Dependent Composition and Molar Extinction Coefficient of PbSe Semiconductor Nanocrystals. ACS Nano 3 (2009), 1518

8. C. Liu, S. Jiang, Y. Sui,* Y. Chen, G. Xiao, X. Chen, H. Shu, and B. Zou,* Effect of the Inherent Structure of Rh Nanocrystals on the Hydriding Behavior under Pressure. J. Phys. Chem. Lett. 10 (2019), 774 (富氢材料)

 

高压下超分子材料研究,高压相的截获及其在高能密度材料和富氢材料中的应用

1. Q. Li, X. Sha, S. Li, K. Wang, Z. Quan, Y. Meng, and B. Zou,* High-Pressure Effects on Hofmann-Type Clathrates: Promoted Release and Restricted Insertion of Guest Molecules. J. Phys. Chem. Lett. 8 (2017), 2745

2. K. Wang, D. Duan, R. Wang, D. Liu, L. Tang, T. Cui, B. Liu, Q. Cui, J. Liu, B. Zou,* and G. Zou, Pressure-Induced Phase Transition in Hydrogen-Bonded Supramolecular Adduct Formed by Cyanuric Acid and Melamine. J. Phys. Chem. B 113 (2009), 14719 (高压相截获)

3. S. Li, Q. Li, J. Zhou, R. Wang, Z. Jiang, K. Wang, D. Xu, J. Liu, B. Liu, G. Zou, and B. Zou,* Effect of High Pressure on the Typical Supramolecular Structure of Guanidinium Methanesulfonate. J. Phys. Chem. B 116 (2012), 3092 (高压相截获)

4. S. Li, Q. Li, R. Li, J. Liu, K. Yang, B. Liu, and B. Zou,* New Assembly of Acetamidinium Nitrate Modulated by High Pressure. J. Phys. Chem. C 118 (2014), 23443 (高压相截获,高能密度材料)

5. S. Li, Q. Li, K. Wang, M. Zhou, X. Huang, J. Liu, K. Yang, B. Liu, T. Cui, G. Zou, and B. Zou,* Pressure-Induced Irreversible Phase Transition in the Energetic Material Urea Nitrate: A Combined Raman Scattering and X-ray Diffraction Study. J. Phys. Chem. C 117 (2013), 152 (高压相截获,高能密度材料)

6. R. Wang, S. Li, K. Wang, D. Duan, L. Tang, T. Cui, B. Liu, Q. Cui, J. Liu, B. Zou,* and G. Zou, Pressure-induced Phase Transition in Hydrogen-Bonded Supramolecular Structure: Guanidinium Nitrate. J. Phys. Chem. B 114 (2010), 6765 (高能密度材料)

7. T. Yan, K. Wang, X. Tan, J. Liu, B. Liu, and B. Zou,* Exploration of the Hydrogen-Bonded Energetic Material Carbohydrazide at High Pressures. J. Phys. Chem. C 118 (2014), 22960 (高能密度材料)

8. S. Li, Q. Li, K. Wang, X. Tan, M. Zhou, B. Li, B. Liu, G. Zou, and B. Zou,* Pressure-Induced Phase Transition in Guanidinium Perchlorate: A Supramolecular Structure Directed by Hydrogen Bonding and Electrostatic Interactions. J. Phys. Chem. B 115 (2011), 11816 (高能密度材料)

9. G. Qi, K. Wang,* G. Xiao, and B. Zou,* High Pressure, a Protocol to Identify the Weak Dihydrogen Bonds: Experimental Evidence of C—H···H—B Interaction. Sci. China Chem. 61 (2018), 276 (富氢材料,压力解决科学中争议的问题

10. G. Qi, K. Wang, X. Li, and B. Zou,* High Pressure Behavior of Hydrogen Storage Material Guanidinium Borohydride. J. Phys. Chem. C 120 (2016), 13414 (富氢材料)

11. G. Qi, K. Wang,* K. Yang, and B. Zou,* Pressure Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds. J. Phys. Chem. C 120 (2016), 21293 (富氢材料)

 

书和综述

1. B. Zou, K. Wang, S. Li and G. Zou, Chapter 11: Synchrotron Radiation Applications on High-Pressure Research. Synchrotron Radiation Applications, [Ed. Xinyi Zhang] World Scientific, 2018

2. L. Zhang, K. Wang,* and B. Zou,* Bismuth Halide Perovskite-Like Materials: Current Opportunities and Challenges. ChemSusChem 12 (2019), 1612

3. T. Geng, C. Liu, G. Xiao,* S. Lu,* and B. Zou,* Advances in the application of high pressure in carbon dots. Mater. Chem. Front. 3 (2019), 2617

 

 


教育经历

[1] 1999.9-2002.12
吉林大学 | 高分子化学与物理 | 博士研究生毕业 | 博士学位
[2] 1996.9-1999.6
吉林大学 | 物理化学 | 硕士研究生毕业 | 硕士学位
[3] 1992.9-1996.6
吉林大学 | 物理化学 | 大学本科毕业 | 学士学位

工作经历

[1] 2006.1-至今
 吉林大学 
[2] 2003.2-2005.12
 德国多特蒙德大学 
[3] 2001.8-2002.8
 德国明斯特大学 

研究方向

[1]高压物理,高压化学

社会兼职

[1]2018.11-至今
中国化学会光化学专业委员会委员
[2]2017.8-至今
第1届亚洲高压科学技术理事会理事
[3]2016.12-至今
中国晶体学会第6届理事会理事
[4]2018.1-至今
中国材料研究学会极端条件材料与器件分会委员会副主任委员

团队成员

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