赵晓,吉林大学“唐敖庆学者”领军教授A岗,国家级青年人才,长白山特聘青年拔尖人才,博士毕业于中科院长春应化所,先后在新加坡国立大学,日本电气通信大学和SPring-8从事科研工作,2021年加入吉林大学,开展氢能、燃料电池和原位表征领域的工作,研究聚焦“催化中心的原位动态追踪与解析”和“高效膜电极的设计与制备”。研究特色是联用谱学电化学工具,以期在催化电极上同时获取催化性能、催化中心和中间体的原位动态演变信息,并结合理论光谱模拟计算,建立构效关系,进而指导催化剂和膜电极的可控制备。
学术论文:截止2023年,以第一/通讯作者在Science, PNAS, JACS, AM和EES等国际主流刊物发表论文20余篇。
在研项目:承担/参与国家基金委自然科学优秀青年项目(海外)和国家重点研发计划子项目等项目,在研经费累计500余万。
招生招聘:课题组目前经费充足,每年均有硕博名额,欢迎同学们报考。
1. 学位硕士,材料物理与化学专业
2. 专业硕士,材料与化工专业
3. 博士研究生,电化学、材料、物理等方向均可
4. 博士后,新能源材料与器件方向,课题组常年高薪招聘博士后人才开展合作研究
教育经历:
1. 2007-2013 中科院长春应化所,博士研究生
2. 2003-2007 湘潭大学,学士
工作经历:
1. 2021-至今 吉林大学,教授
2. 2014-2020 日本电气通信大学,特任助理教授
3. 2013-2014 新加坡国立大学,Research Fellow
获奖荣誉:
1. 国家级高层次人才青年项目,2021
2. 首批长白山特聘青年拔尖人才,2021
3. 博士研究生国家奖学金, 2012
社会兼职:
1. eScience 青年编委,2022-
2. Renewables 青年编委,2023-
课题方向:
1. 氢能与燃料电池电催化材料,包括HER, HOR OER, ORR
2. 高效膜电极的制备与表征, 包括燃料电池和电解水器件
3. 谱学电化学表征技术,包括XAFS,DEMS
4. 电催化与电合成,包括CO2RR,N2RR
5. 金属-空气电池
在研项目(在研经费累计500余万):
1. 国家高层次人才青年项目,2022-2024
2. 国家重点研发子项目-高稳定低铱催化剂结构精准构筑于高一致性批量制备, 2021-2024
3. 吉林大学学科交叉青年创新团队-“绿氢”制备,2022-
4. 中央高校优秀青年团队培育项目,2023-
5. 吉林大学“碳中和”团队,2022-
6. 吉林大学启动经费,2021-2025
论文列表:* 通讯作者,# 共同一作
# 2023
56. Tiantian Zhao#, Kai Chen#, Xiaochun Xu, Xinyi Li, Xiao Zhao*, Qinghai Cai, Ke Chu* and Jingxiang Zhao*, Homonuclear dual-atom catalysts embedded on N-doped graphene for highly efficient nitrate reduction to ammonia: From theoretical prediction to experimental validation, Applied Catalysis B: Environmental, 2023, 339, 123156.
55. Fa Yang# , Ping Song#, Xin Ge, Yan Wang, Takao Gunji, Wei Zhang*, Xiao Zhao*, and Weilin Xu*, Operando analysis reveals potential-driven in situ formation of single-Fe-atom electrocatalysts for green production of ammonia, Proceedings of the National Academy of Sciences, 2023, 120, e2301011120.
54. Xiao Zhao*, Shinobu Takao, Yusuke Yoshida, Takuma Kaneko, Takao Gunji, Kotaro Higashi, Tomoya Uruga, Yasuhiro Iwasawa*,Roles of structural defects in polycrystalline platinum nanowires for enhanced oxygen reduction activity, Appl. Catal. B, 2023, 324: 122268.
53. Jinchang Fan#, Zhipeng Feng#, Yajing Mu, Xin Ge, Dewen Wang, Lei Zhang, Xiao Zhao, Wei Zhang, David J Singh, Jingyuan Ma, Lirong Zheng, Weitao Zheng*, Xiaoqiang Cui*, J. Am. Chem. Soc., 2023, DOI.org/10.1021/jacs.2c11692.
# 2022
52. Jiandong Wu, Xiao Zhao*, Xiaoqiang Cui*, Weitao Zheng*, Emerging two-dimensional metallenes: Recent advances in structural regulations and electrocatalytic applications, Chinese J. Catal., 2023, 43(11): 2802-2814.
51. Xiaowen Ruan, Zhongxu Wang, Zhong Wei, Haiyan Zhang, Lei Zhang, Xiao Zhao, David J Singh, Jingxiang Zhao*, Xiaoqiang Cui*, Weitao Zheng*, Appl. Surf. Sci., 2023, 601: 154294.
50. Qi Hao#, Hai-xia Zhong#, Jia-zhi Wang#, Kai-hua Liu#, Jun-min Yan, Zhou-hong Ren, Na Zhou, Xiao Zhao, Hao Zhang, Dong-xue Liu, Xi Liu, Li-wei Chen, Jun Luo, Xin-bo Zhang*, Nickel dual-atom sites for electrochemical carbon dioxide reduction, Nature Synthesis, 2022, 1(9): 719-728.
49. Jiandong Wu, Jinchang Fan*, Xiao Zhao, Ying Wang, Dewen Wang, Hongtai Liu, Lin Gu, Qinghua Zhang, Lirong Zheng, David J Singh, Xiaoqiang Cui*, Weitao Zheng, Atomically Dispersed MoOx on Rhodium Metallene Boosts Electrocatalyzed Alkaline Hydrogen Evolution, Angew. Chem. Int. Ed., 2022, 61(34): e202207512.
48. Xingcheng Ma, Feng Wang, Dongxu Jiao, Dantong Zhang, Xiao Zhao, David J Singh, Jingxiang Zhao*, Xiaoqiang Cui*, Weitao Zheng, Room-temperature liquid metal synthesis of nanoporous copper-indium heterostructures for efficient carbon dioxide reduction to syngas, Sci. China Mater., 2022, 65(12): 3504-3512.
47. Xiaowen Ruan, Xiaoqiang Cui*, Yi Cui, Xiaofeng Fan, Zhiyun Li, Tengfeng Xie, Kaikai Ba, Guangri Jia, Haiyan Zhang, Lei Zhang, Wei Zhang, Xiao Zhao, Jing Leng, Shengye Jin, David J Singh, Weitao Zheng, Favorable Energy Band Alignment of TiO2 Anatase/Rutile Heterophase Homojunctions Yields Photocatalytic Hydrogen Evolution with Quantum Efficiency Exceeding 45.6%, Adv. Energy Mater., 2022, 12(16): 2200298.
#2021
46. Xiao Zhao*, Takao Gunji, Fan Lv, Bolong Huang,* Rui Ding, Jianguo Liu*, Mingchuan Luo, Zhigang Zou, and Shaojun Guo*, Direct Observation of Heterogeneous Surface Reactivity and Reconstruction on Terminations of Grain Boundaries of Platinum, ACS Mater. Lett., 2021 3(5): 622-629.
45. Rongpeng Ma#, Ying Wang#, Guoqiang Li, Long Yang, Shiwei Liu, Zhao Jin, Xiao Zhao*, Junjie Ge*, and Wei Xing*, Tuning the oxidation state of Ru to surpass Pt in hydrogen evolution reaction, Nano Research, 2021, 14(11): 4321-4327.
44. Ying Wang, Guangri Jia, Xiaoqiang Cui*, Xiao Zhao, Qinghua Zhang, Lin Gu, Lirong Zheng, Lu Hua Li, Qiong Wu, David J Singh, Daiju Matsumura, Takuya Tsuji, Yi-Tao Cui, Jingxiang Zhao*, Weitao Zheng, Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity, Chem, 2021, 7(2): 436-449.
#2020
43. Meiling Xiao#, Zihao Xing#, Zhao Jin, Changpeng Liu, Junjie Ge, Jianbing Zhu*, Ying Wang*, Xiao Zhao*, and Zhongwei Chen*, Preferentially Engineering FeN4 Edge Sites onto Graphitic Nanosheets for Highly Active and Durable Oxygen Electrocatalysis in Rechargeable Zn-Air Batteries, Adv. Mater., 2020, 32(49): 2004900.
42. Xin Luo, Xiaoqian Wei, Hengjia Wang, Wenling Gu, Takuma Kaneko, Yusuke Yoshida, Xiao Zhao*, Chengzhou Zhu*, Secondary-Atom-Doping Enables Robust Fe–N–C Single-Atom Catalysts with Enhanced Oxygen Reduction Reaction, Nano-Micro Lett., 2020, 12(1): 163.
41. Fang Luo#, Hao Hu#, Xiao Zhao#, Zehui Yang*, Quan Zhang, Jingxiang Xu*, Takuma Kaneko, Yusuke Yoshida, Chengzhou Zhu* and Weiwei Cai*, Robust and Stable Acidic Overall Water Splitting on Ir Single Atoms, Nano Lett., 2020,20(3): 2120-2128. IF 11.238.
40. Xiao Zhao*#, Takao Gunji#, Takuma Kaneko#, Shinobu Takao, Tomohiro Sakata, Kotaro Higashi, Yusuke Yoshida, Junjie Ge, Changpeng Liu, Wei Xing*, Jianbing Zhu, Meiling Xiao, Tomoya Uruga, Franklin Feng Tao and Zhongwei Chen*, Evidence for Interfacial Geometric Interactions at Metal-Support Interfaces and Its Influence on the Electroactivity and Stability of Pt Nanoparticles, J. Mater. Chem. A, 2020, 8(3): 1368-1377.
39. Xiao Zhao, Yutaka Hamamura, Yusuke Yoshida, Takuma Kaneko, Takao Gunji, Shinobu Takao, Kotaro Higashi, Tomoya Uruga, and Yasuhiro Iwasawa*, Plasma-Devised Pt/C Model Electrodes for Understanding the Doubly Beneficial Roles of a Nanoneedle-Carbon Morphology and Strong Pt-Carbon Interface in the Oxygen Reduction Reaction, ACS Appl. Energy Mater., 2020, 3(6): 5542-5551.
38. Jianbing Zhu, Shuang Li, Meiling Xiao, Xiao Zhao, Gaoran Li, Zhengyu Bai, Matthew Li, Yongfeng Hu, Renfei Feng, Wenwen Liu, Rui Gao, Dong Su, Aiping Yu, Zhongwei Chen, Tensile-strained ruthenium phosphide by anion substitution for highly active and durable hydrogen evolution, Nano Energy, 2020, 77: 105212.
#2019
37. Xinlong Tian#, Xiao Zhao#, Ya-Qiong Su#, Lijuan Wang, Hongming Wang, Dai Dang, Bin Chi, Hongfang Liu, Emiel J.M. Hensen, Xiong Wen (David) Lou*, and Bao Yu Xia*, Engineering Bunched PtNi Alloy Nanocages for Efficient Oxygen Reduction in Practical Fuel Cells, Science, 2019, 366(6467): 850-856.
36. Xiao Zhao*, Takao Gunji, Takuma Kaneko, Yusuke Yoshida, Shinobu Takao, Kotaro Higashi, Tomoya Uruga, Wenxiang He, Jianguo Liu*, Zhigang Zou, An Integrated Single-Electrode Method Reveals the Template Roles of Atomic Steps: Disturb Interfacial Water Networks and thus Affect the Reactivity of Electrocatalysts, J. Am. Chem. Soc., 2019, 141(21): 8516-8526.
35. Xiao Zhao, Shinobu Takao, Takuma Kaneko, Yasuhiro Iwasawa, Key Factors for Simultaneous Improvements of Performance and Durability of Core-Shell Pt3Ni/Carbon Electrocatalysts Toward Superior Polymer Electrolyte Fuel Cell, Chem Rec, 2019, 19 (7): 1337-1353.
34. Meiling Xiao#, Yongting Chen#, Jianbing Zhu#, Hao Zhang, Xiao Zhao, Liqin Gao, Xian Wang, Jin Zhao, Junjie Ge*, Zheng Jiang*, Shengli Chen*, Changpeng Liu and Wei Xing*, Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering, J. Am. Chem. Soc., 2019, 141(44): 17763-17770.
33. Jiaxi Zhang, Xiao Zhao, Li Du, Yutao Li, Longhai Zhang, Shijun Liao, John B Goodenough, Zhiming Cui, Antiperovskite Nitrides CuNCo3–xVx: Highly Efficient and Durable Electrocatalysts for the Oxygen-Evolution Reaction, Nano Lett., 2019,19(10): 7457-7463.
#2018
32. Shinobu Takao, Oki Sekizawa, Gabor Samjeské, Takuma Kaneko, Kotaro Higashi, Yusuke Yoshida*, Xiao Zhao, Tomohiro Sakata, Takashi Yamamoto, Takao Gunji, Tomoya Uruga, and Yasuhiro Iwasawa,Observation of Degradation of Pt and Carbon Support in Polymer Electrolyte Fuel Cell Using Combined Nano-X-ray Absorption Fine Structure and Transmission Electron Microscopy Techniques. ACS Appl. Mater. Interfaces, 2018 10(33): 27734-27744.
31. Oki Sekizawa,Takuma Kaneko1,Kotaro Higashi1,Shinobu Takao1,Yusuke Yoshida, Takao Gunji,Xiao Zhao,Gabor Samjeské,Tomohiro Sakata,Tomoya Uruga,and Yasuhiro Iwasawa*, Key Structural Transformations and Kinetics of Pt Nanoparticles in PEFC Pt/C Electrocatalysts by a Simultaneous Operando Time-Resolved QXAFS–XRD Technique,Topics in Catalysis,2018,61(9): 889-901.
#2017
30. Xiao Zhao, Shinobu Takao, Kotaro Higashi, Takuma Kaneko, Gabor Samjeskè, Oki Sekizawa, Tomohiro Sakata, Yusuke Yoshida, Tomoya Uruga, Yasuhiro Iwasawa*, Simultaneous Improvements in Performance and Durability of an Octahedral PtNix/C Electrocatalyst for Next-Generation Fuel Cells by Continuous, Compressive, and Concave Pt Skin Layers, ACS Catal., 2017, 7(7): 4642-4654.
#2016
29. Jianbing Zhu, Meiling Xiao, Kui Li, Changpeng Liu, Xiao Zhao*, Wei Xing, Active Pt3Ni (111) Surface of Pt3Ni Icosahedron for Oxygen Reduction, ACS Appl. Mater. Interfaces, 2016, 8(44): 30066-30071.
28. Takuma Kaneko, Gabor Samjeské, Shin-ichi Nagamatsu, Kotaro Higashi, Oki Sekizawa, Shinobu Takao, Takashi Yamamoto, Xiao Zhao, Tomohiro Sakata, Tomoya Uruga, and Yasuhiro Iwasawa*, Key Structural Kinetics for Carbon Effects on the Performance and Durability of Pt/Carbon Cathode Catalysts in Polymer Electrolyte Fuel Cells Characterized by In Situ Time-Resolved X-ray Absorption Fine Structure, J. Phys. Chem. C, 2016, 120(42): 24250-24264.
27. Shinobu Takao, Oki Sekizawa, Gabor Samjeské, Shin-ichi Nagamatsu, Takuma Kaneko, Kotaro Higashi, Takashi Yamamoto, Kensaku Nagasawa, Xiao Zhao, Tomoya Uruga, Yasuhiro Iwasawa, Spatially non-uniform degradation of Pt/C cathode catalysts in polymer electrolyte fuel cells imaged by combination of nano XAFS and STEM-EDS techniques, Top Catal., 2016, 59(19): 1722-1731.
#2015
26. Xiao Zhao*, Jian Zhang, Liangjun Wang, He Xing Li, Zhaolin Liu*, Wei Chen*, Ultrathin PtPdCu Nanowires Fused Porous Architecture with 3D Molecular Accessibility: An Active and Durable Platform for Methanol Oxidation, ACS Appl. Mater. Interfaces, 2015, 7(47): 26333-26339.
25. Jianbing Zhu, Meiling Xiao, Xiao Zhao, Changpeng Liu, Wei Xing*, Titanium dioxide encapsulated in nitrogen-doped carbon enhances the activity and durability of platinum catalyst for Methanol electro-oxidation reaction. J. Power Sources, 2015, 292, 78-86.
24. Jianbing Zhu, Meiling Xiao, Xiao Zhao, Changpeng Liu, Junjie Ge*, Wei Xing*, Strongly coupled Pt nanotubes/N-doped graphene as highly active and durable electrocatalysts for oxygen reduction reaction, Nano Energy, 2015, 13, 318-326.
23. Jian Zhang, Liangjun Wang, Leilei Xu, Xiaoming Ge, Xiao Zhao, Min Lai, Zhaolin Liu* and Wei Chen*, Porous cobalt-manganese oxide nanocubes derived from metal organic frameworks as a cathode catalyst for rechargeable Li-O2 batteries, Nanoscale, 2015, 7 (2), 720-726.
22. Liang Yan, Weiwei Cai, Xiao Zhao, Liang Liang,Wei Xing*, and Changpeng Liu*, Investigation of a New Method to Prepare Low Methanol and Water Crossover Membrane Electrode Assembly for Passive Direct Methanol Fuel Cells. Energy and Environment Focus, 2015, 4 (1), 1-7.
21. Liang Jun Wang, Jian Zhang, Xiao Zhao, Lei Lei Xu, Zhi Yang Lyu, Min Lai and Wei Chen*, Palladium nanoparticle functionalized graphene nanosheets for Li-O2 batteries: enhanced performance by tailoring the morphology of the discharge product. RSC Adv., 2015, 5 (90), 73451-73456.
#2014
20. Xiao Zhao, Jianbing Zhu, Liang Liang, Chenyang Li, Changpeng Liu*, Jianhui Liao, Wei Xing*, Biomass-derived N-doped carbon and its application in electrocatalysis, Appl. Catal. B, 2014, 154, 177-182.
19. Xiao Zhao, Zhang Jian, Liangjun Wang, Zhaolin Liu*, Wei Chen*, PdxCu100-x networks: an active and durable electrocatalyst for ethanol oxidation in alkaline medium, J. Mater. Chem. A, 2014, 2 (48), 20933-20938.
18. Jianbing Zhu, Xiao Zhao, Meiling Xiao, Liang Liang, Changpeng Liu, Jianhui Liao, and Wei Xing*, The construction of nitrogen-doped graphitized carbon-TiO2 composite to improve the electrocatalyst for methanol oxidation. Carbon, 2014, 72, 114-124.
17. Jianbing Zhu, Meiling Xiao, Xiao Zhao, Kui Li, Changpeng Liu, and Wei Xing*, Nitrogen-doped carbon–graphene composites enhance the electrocatalytic performance of the supported Pt catalysts for methanol oxidation. Chem. Commun., 2014, 50 (81), 12201-12203.
16. Jian Zhang, Yubao Zhao, Xiao Zhao, Zhaolin Liu* and Wei Chen*, Porous Perovskite LaNiO3 Nanocubes as Cathode Catalysts for Li-O2 Batteries with Low Charge Potential, Scientific Reports, 2014, 4, 6005.
15. Meiling Xiao, Songtao Li, Xiao Zhao, Jianbing Zhu, Min Yin, Changpeng Liu*, and Wei Xing*, Enhanced Catalytic Performance of Composition-Tunable PtCu Nanowire Networks for Methanol Electrooxidation. Chemcatchem, 2014, 6 (10), 2825-2831.
14. Kui Li, Jianbing Zhu, Meiling Xiao, Xiao Zhao, Shikui Yao, Changpeng Liu*, and Wei Xing*, Promotion of Mesoporous Vanadium Carbide Incorporated on Resorcinol-Formaldehyde Resin Carbon Composites with High-Surface-Areas on Platinum Catalysts for Methanol Electrooxidation. Chemcatchem, 2014, 6 (12), 3387-3395.
#2013
13. Xiao Zhao, Jianbing Zhu, Liang Liang, Chenyang Li, Changpeng Liu, Wei Xing, Surface reconstruction enhancing activity of Pt/C for formic acid electrooxidation by ultrasonic mixing with Pb/C and electrochemical activation process, Appl. Catal. B, 2013, 129, 146-152. IF 16.683.
12. Xiao Zhao, Jianbing Zhu, Weiwei Cai, Meiling Xiao, Liang Liang, Changpeng Liu, Wei Xing, Pt-Pb hollow sphere networks: self-sacrifice-templating method and enhanced activity for formic acid electrooxidation, RSC Adv., 2013, 3 (6), 1763-1767. IF 3.119.
11. Yang Hu, Xiao Zhao, Yunjie Huang, Qingfeng Li, Niels J. Bjerrum, Changpeng Liu*, Wei Xing*, Synthesis of self-supported non-precious metal catalysts for oxygen reduction reaction with preserved nanostructures from the polyaniline nanofiber precursor, J. Power Sources, 2013, 225, 129-136.
10. Liang Yan, Jianhui Liao, Ligang Feng, Xiao Zhao, Liang Liang, Wei Xing*, and ChangpengLiu*, Developing and performance measurements for a novel miniaturized electrochemical methanol sensor, J. Electroanal. Chem., 2013, 688: 49-52.
#2012
9. Xiao Zhao, Jianbing Zhu, Liang Liang, Changpeng Liu, Jianhui Liao, Wei Xing*, Enhanced electroactivity of Pd nanocrystals supported on H3PMo12O40/carbon for formic acid electrooxidation, J. Power Sources, 2012, 210, 392-396.
8. Xiao Zhao, Jianbing Zhu, Liang Liang, Jianhui Liao, Changpeng Liu*, Wei Xing*, Enhanced activity of Pt nanocrystals supported on a novel TiO2@ N-doped C nano-composite for methanol oxidation reaction, J. Mater. Chem., 2012, 22 (37), 19718-19725.
7. Xiao Zhao, Yang Hu, Liang Liang, Changpeng Liu, Jianhui Liao, Wei Xing, Ionic liquid-mediated synthesis of 'clean' palladium nanoparticles for formic acid electrooxidation, Int. J. Hydrog. Energy, 2012, 37 (1), 51-58.
6. Shikui Yao, Ligang Feng, Xiao Zhao, Changpeng Liu, and Wei Xing*, Pt/C catalysts with narrow size distribution prepared by colloidal-precipitation method for methanol electrooxidation, J. Power Sources, 2012, 217, 280-286.
5. Qing Lv, Min Yin, Xiao Zhao, Chenyang Li, Changpeng Liu*, and Wei Xing*, Promotion effect of TiO2 on catalytic activity and stability of Pt catalyst for electrooxidation of methanol. J. Power Sources, 2012, 218, 93-99.
4. Ligang Feng, Shikui Yao, Xiao Zhao, Liang Yan, Changpeng Liu, and Wei Xing*, Electrocatalytic properties of Pd/C catalyst for formic acid electrooxidation promoted by europium oxide, J. Power Sources, 2012, 197, 38-43.
#2011
3. Xiao Zhao, Min Yin, Liang Ma, Liang Liang, Changpeng Liu, Jianhui Liao, Tianhong Lu, Wei Xing, Recent advances in catalysts for direct methanol fuel cells, Energy Environ. Sci. 2011, 4 (8), 2736-2753.
2. Ligang Feng, Xiao Zhao, Jing Yang, Wei Xing*, and Changpeng Liu, Electrocatalytic activity of Pt/C catalysts for methanol electrooxidation promoted by molybdovanadophosphoric acid. Catal. Commun., 2011, 14 (1), 10-14.
#2010
1. Liang Ma, Xiao Zhao, Fengzhan Si, Changpeng Liu, Jianhui Liao, Liang Liang, and Wei Xing*, A comparative study of Pt/C and Pt-MoOx/C catalysts with various compositions for methanol electro-oxidation. Electrochim. Acta, 2010, 55 (28), 9105-9112.