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Synthesis of Crystalline Porous Organic Salts with High Proton Conductivity

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发布时间:2019-03-25

论文类型:期刊论文

论文编号:10.1002/anie.201800423

第一作者:Xing, Guolong

通讯作者:Ben,Teng

全部作者:Yan, Tingting,Qiu, Shilun,Das, Saikat

发表时间:2018-05-04

发表刊物:Angewandte Chemie-International Edition

发表刊物: SCI 

所属单位:吉林大学化学学院

学科门类:理学

项目来源: the NSFC (Grant no. 21390394, 21471065) and the "111" project (B07016)

卷号:57

期号:19

页面范围: 5345-5349

ISSN号:1433-7851

关键字:CO2 adsorption; crystalline porous organic salts; polar channels; proton conductivity

摘要:Self-assembled crystalline porous organic salts (CPOSs) formed by an acid-base combination and with one-dimensional polar channels containing water molecules have been synthesized. The water content in the channels of the porous salts plays an important role in the proton conduction performance of the materials. The porous salts described in this study feature high proton conductivity at ambient conditions and can reach as high as 2.2x10(-2)Scm(-1) at 333K and under high humid conditions. This is among the best conductivity values reported to date for porous materials, for example, metal-organ

一级学科:化学

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