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发布时间：2019-03-25

论文类型：期刊论文

论文编号：10.1002/anie.201804383

第一作者：Das, Saikat

通讯作者：Ben，Teng

全部作者：Xu, Shixian,Qiu, Shilun

发表时间：2018-07-09

发表刊物：Angewandte Chemie-International Edition

发表刊物： SCI 

所属单位：吉林大学化学学院

学科门类：理学

项目来源： the NSFC (No. 21390394, 21471065) and the Science and Technology Department of Jilin Province Founda

卷号：57

期号：28

页面范围： 8629-8633

ISSN号：1433-7851

关键字：chiral induction; chirality; host-guest complexes; metal-organic frameworks; mixed-matrix memb

摘要：Endowed with chiral channels and pores, chiral metal-organic frameworks (MOFs) are highly useful; however, their synthesis remains a challenge given that most chiral building blocks are expensive. Although MOFs with induced chirality have been reported to avoid this shortcoming, no study providing evidence for the eevalue of such MOFs has yet been reported. We herein describe the first study on the efficiency of chiral induction in MOFs using inexpensive achiral building blocks and fully recoverable chiral dopants to control the handedness of racemic MOFs. This method yielded chirality-enriche

一级学科：化学

是否译文：否