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    XU YAN
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"Ternary supramolecular ensembles of cellulose nanocrystals exhibiting multiscale deformation and mechano/chemo-responsive selective reflection of circularly polarized light"

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论文类型 : 期刊论文
第一作者 : Y.Y. Sun,W. Fan
通讯作者 : Y. Xu
全部作者 : J.Q. Liu,L.H. Wei,C. Zou
发表时间 : 2019-03-05
发表刊物 : ACS Sustainable Chem. Eng
学科门类 : 理学
一级学科 : 化学
卷号 : 7
页面范围 : 6851
关键字 : Cellulose nanocrystals; Helical superstructure; Selective reflection of circularly polarized light;
摘要 : Strong and tough structural materials are a challenging materials engineering problem that has drawn considerable attention among the materials community. Here we demonstrate that ternary supramolecular ensembles of cellulose nanocrystals-polyvinyl alcohol-glucose by evaporation-induced corporative assembly achieved simultaneous enhancement on the stiffness and toughness with the Young’s modulus of 13 GPa at the work-of-fracture of 1.1 MJ·m–3. Compositional alteration led to stiff and tough ternary ensembles with the Young’s modulus up to 14.7 GPa and the toughness up to 12.1 MJ·m–3, respectiv
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