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论文成果

Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film

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发布时间:2019-03-23

论文类型:期刊论文

论文编号:10.1002/anie.201402950

第一作者:Lu, Chunjing

通讯作者:Ben,Teng,Qiu, Shilun

全部作者:Xu, Shixian

发表时间:2014-06-06

发表刊物:Angewandte Chemie International Edition

发表刊物: SCI 

所属单位:化学学院

学科门类:理学

项目来源: the National Natural Science Foundation of China (21390394), the National Basic Research Program of

卷号:53

期号:25

页面范围: 6454-6458

ISSN号:1433-7851

关键字:adsorption; conducting polymers; electrochemical synthesis; metal-organic frameworks; polyanil

摘要:A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m(2) g(-1) and a high electric conductivity of 0.125 S cm(-1) when doped with I-2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.

一级学科:化学

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