Indexed by:Journal paper
Document Code:10.1039/c8sc04376k
First Author:Xing, Guolong
Correspondence Author:Ben, Teng,Comotti, Angiolina,Sozzani, Piero
All the Authors:Bezuidenhout, Charl,Negroni, Mattia,Bracco, Silvia,Bassanetti, Irene Date of Publication:2019-01-21
Journal:Chemical Science
Journal: SCI 
Affiliation of Author(s):吉林大学化学学院
Discipline:理学
Funded by:he NSFC (Grant no. 21390394, 21471065) and the "111" project (B07016).
Volume:10
Issue:3
Page Number:730-736
ISSN No.:2041-6520
Key Words:METAL-ORGANIC FRAMEWORKS; POROUS POLYMER NETWORKS; CARBON-DIOXIDE; MOLECULAR-CRYSTALS;
Abstract:Porous molecular materials represent a new front in the endeavor to achieve high-performance sorptive properties and gas transport. Self-assembly of polyfunctional molecules containing multiple charges, namely, tetrahedral tetra-sulfonate anions and bifunctional linear cations, resulted in a permanently porous crystalline material exhibiting tailored sub-nanometer channels with double helices of electrostatic charges that governed the association and transport of CO2 molecules. The charged channels were consolidated by robust hydrogen bonds. Guest recognition by electrostatic interactions remi
First-Level Discipline:化学
Translation or Not:no