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Ben Teng

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Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film
2014-06-06  Hits:

Indexed by:Journal paper
Document Code:10.1002/anie.201402950
First Author:Lu, Chunjing
Correspondence Author:Ben,Teng,Qiu, Shilun
All the Authors:Xu, Shixian Date of Publication:2014-06-06
Journal:Angewandte Chemie International Edition
Journal: SCI 
Affiliation of Author(s):化学学院
Discipline:理学
Funded by:the National Natural Science Foundation of China (21390394), the National Basic Research Program of
Volume:53
Issue:25
Page Number:6454-6458
ISSN No.:1433-7851
Key Words:adsorption; conducting polymers; electrochemical synthesis; metal-organic frameworks; polyanil
Abstract:A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m(2) g(-1) and a high electric conductivity of 0.125 S cm(-1) when doped with I-2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.
First-Level Discipline:化学
Translation or Not:no